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Молекулярные перегруппировки циклополиенов

56250

Михайлов И.Е.

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The monograph summarizes and systematizes data on the fluctuating behavior of cyclopolyenes associated with rapid displacements of element-centered migrants along the periphery of 3-9-membered cycles. It has been shown that, depending on the ring size, the nature of the migrant, substituents in the ring, and the medium, the rate constants of circular rearrangements cover a wide frequency range: from 106 to 10~8 s-1 at room temperature. Particular attention is paid to the experimental and theoretical analysis of the various mechanisms responsible for these rearrangements and the correlation of the preferred mechanisms with the structural characteristics of the rearranged compounds. Ways of practical application of fluctuating cyclopolyenes are considered. For organic chemists, physical chemists and a wide range of specialists in the field of chemistry.

Data sheet

ISBN 978-5-02-036670-1
Publisher Наука. Москва. 2008
Bookbinding твердый переплет, 230 стр.

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